torsional strain उदाहरण वाक्य
उदाहरण वाक्य
- The above reaction is an example of the stereoelectronic selectivity-based strain relief ( alleviation of 1, 3-diaxial interactions, torsional strain, etc . ).
- Both conformations are free of torsional strain, but, in the gauche conformation, the two methyl groups are in closer proximity than the sum of their van der Waals radii.
- Further work has shown that the effect of 1, 3-dioxanes and 1, 3-dioxolanes on disarming sugars can be attributed to the electronics of the systems as well as torsional strain.
- Then follows a torsional strain relieving rotation to the trans isomer ( not shown ) and step "'C "'is a beta-hydride elimination step with the formation of a new palladium-alkene ? complex ( "'5 "').