carbanion उदाहरण वाक्य
उदाहरण वाक्य
- In the S E 1 course of action the substrate first ionizes into a carbanion and a positively charged organic residue.
- The synthesis proceeds with a nucleophilic attack of the carbanion on the electrophilic carbonyl carbon of the ester or carboxylic acid.
- The phosphorus stabilized carbanion then undergoes an elimination to give the alkene, along with an acyl phosphite, which then decarboxylates.
- In step 2 the negatively charged carbanion combines with ( Y ) that is electron-poor to form the second covalent bond.
- Next, the carbanion resulting from the benzylic hydrogen extraction performs a nucleophilic attack on the electrophilic carbonyl carbon of the amide group.
- This carbanion then binds to the carbonyl of the donor substrate thus cleaving the bond between C-2 and C-3.
- As a consequence, bond rupture between C6 and C7 due to protonation of the former going through a carbanion state has been proposed.
- One distinguishing feature of the dithiolanes and dithianes derived from aldehydes is that the methyne group can be deprotonated and the resulting carbanion alkylated.
- The traditional mechanism attributed to an alanine racemase reaction is that of a two-base mechanism with a PLP-stabilized carbanion intermediate.
- When this center is an electron rich carbanion or an alkoxide anion, the presence of the electron-withdrawing substituent has a stabilizing effect.