enolate उदाहरण वाक्य
उदाहरण वाक्य
- The enolate intermediate discussed earlier is stabilized by residues additional hydrogen bonds to Tyr199 and Asn148.
- It rather promotes conjugate addition by binding to the zwitterionic enolate, and stabilizing these intermediates.
- Z must be powerful enough to facilitate deprotonation to the enolate ion even with a mild base.
- Crossed Claisen condensations, in which the enolate and nucleophile are different esters, are also possible.
- The trimethylsilyl enol ethers can also be used as masked enolate equivalents in the Mukaiyama aldol addition.
- In the scheme shown, the enol or enolate of a methyl ketone reacts with an aldehyde.
- Competing work with lithium enolate aldol reactions was published also in 1973 by Herbert O . House.
- The enolate anion exhibits significant delocalization, and the highest electron density is on the second carbon.
- Because carbonyl compounds are only weakly acidic, a strong base is needed for enolate ion formation.
- In this reaction the rate-limiting step is formation of the enolate by deprotonation of the ketone.