antibonding orbital उदाहरण वाक्य
उदाहरण वाक्य
- Effectiveness for this is in the order diethyl ether < 1, 2-dimethoxyethane < HMPA . In principle any unsaturated molecule can form a radical anion, but the antibonding orbitals are only energetically accessible in more extensive conjugated systems.
- Do you understand how the orbitals are filled in the MO diagram at triplet oxygen, and how to calculate bond order based on filling of bonding and antibonding orbitals ? talk ) 13 : 51, 15 April 2011 ( UTC)
- It was mentioned to me in passing half a year ago how nucleophile electrons attack antibonding orbitals . . . and in fact I had totally forgotten about antibonding orbitals ( as a mechanism for nucleophilic attack ) until it was mentioned again.
- It was mentioned to me in passing half a year ago how nucleophile electrons attack antibonding orbitals . . . and in fact I had totally forgotten about antibonding orbitals ( as a mechanism for nucleophilic attack ) until it was mentioned again.
- This reduction of symmetry lifts the degeneracy of the two formerly non-bonding molecular orbitals, which by Hund's rule forces the two unpaired electrons into a new, weakly bonding orbital ( and also creates a weakly antibonding orbital ).
- The next highest are the ? bonding orbitals which represent the HOMO . Because the 10 valence electrons of the metals are used to fill these first 5 orbitals, the next highest orbital becomes the LUMO which is the ? * antibonding orbital.
- I can't remember what he exactly told me, but years later in my mind, his explanation is somehow jumbled up in my mind as " the attacking nucleophile finds it hard to choose " ( which antibonding orbital to attack ).
- It is therefore classified as an bonding structure between the oxygen atoms is weakened ( i . e ., is higher in energy ) for instance, it is higher in energy than the bonding in dinitrogen, where the corresponding antibonding orbitals are empty.
- The strength of interaction with the counterion affects the energy of this antibonding orbital; thus, in colorless chloryl compounds, strong interactions with the counterion, corresponding with the higher covalent character of the bonding, shift the transition energy out of the visible spectrum.
- A molecular orbital analysis of this phenomenon suggest that this conformation provides the best overlap between the electrons in the R-H ? bonding orbital that is undergoing nucleophilic attack and the empty ? * antibonding orbital of the R-X bond that is being broken.