ketene उदाहरण वाक्य
उदाहरण वाक्य
- Alternately, the pyrolysis can be performed in solution, allowing a one-pot reaction with chemicals already present rather than isolating the unstable ketene intermediate.
- Because it is a dimer, it shares an empirical formula with CO . It can be thought of as ketene of glyoxylic acid ( OHCCOOH ).
- Cyclobutenone was originally synthesized from the 3-bromocyclobutanone and 3-chlorocyclobutanone precursors which were prepared from an allene and a ketene via two independent routes.
- In the exposed regions, the DNQ forms a ketene, which, in turn, reacts with ambient water to form a base soluble indene carboxylic acid.
- A Wolff Rearrangement of the diazoacetoacetate enone ( pink ) forms a stable ketene, which reacts with the imine to form a stable ?-lactam compound.
- In these contexts, it appears that the carbonite ion reacts with excess carbon monoxide to form an anion with the ketene structure, O = C =.
- The tertiary amine contained within the quinuclidine can act as a nucleophile that attacks the most electrophilic carbon of the ketene to promote the formation of ?-lactams.
- The greatest use of thermal Wolff rearrangements is the formation of carboxylic acid analogs, by interception of the ketene with high boiling solvents, such as aniline and phenol.
- The use of 2-chloroacrylonitrile as dienophile is a viable synthetic equivalent for ketene, Hydrolysis of the epimeric mixture of chloronitrile adducts revealed the desired bicycloheptanone in high yield.
- In the proposed reaction mechanism the base first converts the acid chloride to the ketene, the organocatalyst then introduces chirality through its quininoid tertiary amine, forming a ketene adduct.