steric effect उदाहरण वाक्य
उदाहरण वाक्य
- Other important factors include solvent choice, solution pH, steric effects, temperature, and the pressure of hydrogen inside the hydrogenation vessel.
- The regioselectivity of allylation mediated by indium in water is dependent on the steric effects of the substituents on both the intermediate and carbonyl.
- Also, the reaction rate was affected considerably by steric effects of 2-substituents, with more bulky groups increasing the rate of reaction.
- Electrostatic interactions are generally too weak to be considered traditional bonds or are prevented from forming a traditional bond, possibly by a steric effect.
- Steric effects of the alkyl substituents on the carbonyl reactant have been shown to affect both the rates and yields of B�chner Curtius Schlotterbeck reaction.
- Chad Tolman developed his ligand cone angle theory that developed into the widely accepted electronic and steric effects of ligands on inorganic and organometallic complexes.
- Of course, other effects can play a role in this selectivity process, including electronic effects, steric effects, and thermodynamic versus kinetic reaction control.
- A special computational procedure was developed to separate electronic and steric effects of an arbitrary group in the molecule and to reveal their influence on structure and reactivity.
- The "'Taft equation "'is a resonance effects influence reaction rates, the Taft equation also describes the steric effects of a substituent.
- Oftentimes, as with highly substituted dienes or very bulky dienophiles, steric effects can greatly influence " endo " / " exo " selectivity.